Exothermic reactions
When fuel burns
2C8H18(g) + 25O2(g) ® 16CO2(g) + 18H2O(g) DH = - 1393.5 kJ mol-1
Burning coke or charcoal in air or oxygen
C(s) + O2(g) ® CO2(g)
DH = - 393.5 kJ mol-1
Endothermic reactions
When coke burns in carbon dioxide in a blast furnace,
C(s) + CO2(g) ® 2CO(g) DH = + 283 kJ mol-1
Coke burning in steam to make water gas (a mixture of carbon monoxide and hydrogen
C(s) + H2O(g) ® CO(g)
+ H2(g) DH = +132 kJ mol-1